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Add 2ml alkali iodide azide if becomes yellow = oxygen present while no oxygen
ppt will be created let it settle ( Na2S03, Sodium sulphride) brings oxygen to zero
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Add NaS03 to another sample (oxygen become zero)
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Add MnSo4 add alkali iodide axide
color while means no oxygen.
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Add 2ml H2S04 ro disolve (in first sample) color becomes as mastard oil
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Remove 100ml from the sample
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Add 1ml startch indicator to the remaining sample => color = blueish
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Take NaS2o3 in burrete
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Titrate the sample against it until it becomes colorless ==> initial reading=4ml ==> final reading=12.6ml ==>
12.6-4=8.6ml
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++ (oH) 1ml of Na2S03 = 1mgk of dissolved oxygen it contains 8-6 mgk of dissolved oxygen Mn + H2O => M(oH)2
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Mn (oH)2 + 1/2 o2 =>Mno2+ H2O
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Mno2 + 2i + 4H + => Mn + i2 +2 H2O